Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 14, Pages 4288-4290Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10241a
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Hydroboration of the electron poor phosphine (1-propenyl)P(C6F5)(2) with Piers' borane [HB(C6F5)(2)] gave the geminal frustrated Lewis pair (C6F5)(2)P-CH(Et)-B(C6F5)(2). It undergoes 1,2-addition reactions to an alkene and an alkyne and to the C=N bond of an isocyanate. With mesityl azide it undergoes a 1,3-addition reaction.
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