Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 8, Pages 2354-2356Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03844j
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Funding
- National Natural Science Foundation of China [20832001, 20972065, 21074054]
- National Basic Research Program of China [2007CB925103, 2010CB92330]
- Major Scientific and Technological Special Project [2009ZX09103-081]
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Oxidative alpha-cyanation of tertiary amines is catalyzed by gold complexes with trimethylsilyl cyanide to afford the corresponding alpha-aminonitriles in the presence of tert-butyl hydroperoxide in good to excellent yields under acid-free conditions at room temperature.
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