4.7 Article

Chiral porphyrin dimer with a macrocyclic cavity for intercalation of aromatic guests

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 21, Pages 6090-6092

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11572c

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Funding

  1. Japan Science and Technology Agency (JST)
  2. Okayama Foundation for Science and Technology

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Chiral diporphyrin receptor 1, which has a macrocyclic cavity to sandwich aromatic guest molecules via double pi-pi stacking interactions, enabled the naked-eye detection of an aromatic explosive as well as chiral discrimination in NMR.

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