Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 9, Pages 2520-2522Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05302c
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Funding
- NSF of China [20973143, 91027009]
- National Basic Research Program of China (973 Program) [2007CB815303, 2009CB930703]
- Xiamen University [2010121020]
- NCETFJ
- HPC of Xiamen University
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When p-aminothiophenol (PATP) is used as a probe molecule and adsorbs on silver and gold nanogaps, a significant change of relative SERS intensities can be observed. Our DFT calculations show that surface photocatalytic coupling reactions yield a new surface species of p, p'-dimercaptoazobenzene (DMAB) causing the significant change in the SERS spectra.
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