Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 13, Pages 3983-3985Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10129c
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Optically active 1,3-dioxolan-2-yl cation intermediates were generated during enantioselective dioxyacetylation of alkene with chiral hypervalent iodine(III). Regioselective attack of a nucleophile toward the intermediate resulted in reversal of enantioselectivity of the dioxyacetylation.
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