Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 12, Pages 3380-3382Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10143a
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Funding
- EPSRC
- Engineering and Physical Sciences Research Council [EP/C543742/1] Funding Source: researchfish
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Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H(2)bdc) and 2-halo-1,4-benzenedicarboxylic acid (H(2)bdc-X, X = Br or I) to give [Zn(4)O(bdc)(3-x)(bdc-X)(x)], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.
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