Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 40, Pages 11204-11206Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11999k
Keywords
-
Categories
Funding
- Hong Kong Research Grants Council [HKU/CRF/01/08, HKU 700810]
- University Grants Committee of the Hong Kong Special Administrative Region, China [AoE 10/01P]
Ask authors/readers for more resources
A practical protocol has been developed for asymmetric cis-dihydroxylation of electron-deficient alkenes with Oxone catalysed by a manganese complex bearing a chiral tetradentate N(4)-donor ligand affording cis-diols in up to 95% yield with up to 96% ee. Analysis of the reaction mixture by high resolution ESI-MS revealed the formation of a cis-dioxomanganese(V) intermediate.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available