4.7 Article

Synthesis and optical resolution of a Cu(I) double-stranded helicate with ketimine-bridged tris(bipyridine) ligands

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 35, Pages 9795-9797

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13333k

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Funding

  1. Japan Society for the Promotion of Science (JSPS)

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A tetranuclear Cu(I) double-stranded helicate was synthesized from ketimine-bridged tris(bipyridine) ligands and Cu(I) ions, and the racemate was successfully resolved by diastereomeric salt formation using an optically pure phosphate anion followed by anion exchange with NaPF6 without racemization.

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