Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 11, Pages 3263-3265Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05482h
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Funding
- World Premier International Research Center (WPI) initiative on Materials Nanoarchitechtonics (MANA)
- MEXT of Japan [22850019, 21540330]
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The first Ruddlesden-Popper type layered cobalt oxyfluoride, Sr2CoO3F, has been synthesized under a pressure of 6 GPa at 1700 degrees C and shown to adopt a K2NiF4-type structure with distorted square pyramidal coordination around Co and with O/F disorder at the apical sites.
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