4.7 Article

A chiral pi-stacked vinyl polymer emitting white circularly polarized light

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 39, Pages 10996-10998

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13711e

Keywords

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Funding

  1. MEXT [21655037, 22350047, 23655092]
  2. Global COE Program [B01]
  3. Asahi Glass Foundation

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An optically active, pi-stacked poly[2,7-bis(4-tert-butylphenyl)dibenzofulvene] having a preferred-handed helical conformation was synthesized by anionic polymerization. A thin film sample of the polymer exhibited broad-band white circularly polarized light (CPL) emission on photo excitation.

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