Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 31, Pages 8808-8810Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12422f
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Funding
- The University of Hong Kong
- University Grants Council of HKSAR [AoE/P-03/08]
- The Committee on Research and Conference Grants, HKU
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Eight homoleptic metal(III) arylchalcogenolate polymers [M(EPh-p-X)(3)](n) (M = Ru, Cr, and Mo) were characterized by PXRD. Structural solution of [Ru(SPh-p-tBu)(3)](n) 1 was achieved by Rietveld refinement of the PXRD data. Pyrolysis of [Ru(SePh)(3)](n) 4 produced nanostructured RuSe2, which selectively catalyzed the reduction of nitro compounds in the presence of other functionalities.
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