Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 20, Pages 5855-5857Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10869g
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The halogen-bonded adduct between DABCO and two molecules of perfluorooctyl iodide (DABCO center dot(C8F17I)(2)) acts as a recyclable organocatalyst for the Morita-Baylis-Hillman reaction. This supramolecular fluorous catalyst is readily accessible and can be recovered by simple precipitation/filtration.
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