4.7 Article

High-nuclearity, mixed-valence Mn-17, Mn-18 and {Mn-62}(n) complexes from the use of triethanolamine

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 1, Pages 274-276

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01701a

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Funding

  1. National Science Foundation [CHE-0910472]

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The use of both azide and triethanolamine, with or without the presence of carboxylate groups, has provided new Mn-17, Mn-18 and {Mn-62}(n) complexes with aesthetically-pleasing cage, layered, and linked-chain-type structures; two are also new single-molecule magnets.

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