Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 31, Pages 8796-8798Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13286e
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Funding
- NSF [OCE-0963064]
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A simple pyrene-based triazole receptor has been synthesised and shown to self-assemble in the presence of ZnCl2 in an exclusively 2 : 1 ratio, whereas a mixture of 2 : 1 and 1 : 1 ratios are observed for other Zn2+ salts. The pyrene units are syn in orientation; this is supported by a strong excimer signal observed at 410 nm in the presence of ZnCl2 in acetonitrile. DFT calculations and 2D NMR support the proposed structure.
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