4.7 Article

Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 13, Pages 3787-3789

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04689b

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Funding

  1. National Natural Science Foundation of China [20731004, 21021062]
  2. National Basic Research Program of China [2007CB925103, 2010CB923303]

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A unique 4-fold interpenetrated (10,3)-b copper(II) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC-SC) process, and the dehydrated material can encapsulate CH3OH molecules, again in a SC-SC fashion, and shows selective adsorption of H-2 and CO2 over N-2.

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