Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 50, Issue 3-4, Pages 323-338Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970008054938
Keywords
copper(III); review; structures; coordination complexes
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Copper is classed as a transition metal both from its physico-chemical properties and its biochemical behavior. This review includes thirty formally copper(III) compounds where crystal structure has been determined. Coordination number four dominates with mostly a square-planar arrangement about the copper(III) atom. Sulfur donor ligands by far prevail. In general the Cu-L bond distance elongated with a decreased oxidation state of copper in the sequence: Cu(III)-L < Cu(II)-L < Cu(I)-L. Examples of distortion isomerism exist.
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