Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 5, Pages 1461-1463Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04391e
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Funding
- National Natural Science Foundation of China [21071118]
- MSTC [2007CB815301]
- Huaqiao University [10BS210]
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A novel mixed-valent Ag-I/Ag-0 T-h-Ag-34 cage was obtained by a one-pot ultrasonic reaction. In the shell of the cage, CO32- anion is derived from atmospheric CO2 and adopts a rare mu(6) bridging mode to link the Ag-I ions. In the core of the cage, an unprecedented neutral metal cluster with six zero-valent silver atoms is encapsulated.
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