Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 43, Pages 11912-11914Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15072c
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Funding
- UniCat cluster of excellence (Unifying Concepts in Catalysis, Berlin)
- European Commission [212508]
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The atomic structure of an electrodeposited Ni catalyst film is dominated by extensive di-mu-oxido bridging between Ni(III/IV) ions, as revealed by X-ray absorption spectroscopy. The structure is surprisingly similar to that of an analogous Co-based film and colloidal Mn-based catalysts. Structural requirements for water oxidation are discussed.
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