Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 27, Pages 7827-7829Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12800k
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- Marie Curie fellowship
- Wenner-Gren foundation
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Primary carbohydrate amines at primary and secondary carbons are alkylated by alcohols in the presence of [Cp*IrCl2](2). When primary carbohydrate alcohols are used as the coupling partners and in the presence of Cs2CO3, amine-linked pseudodisaccharides are obtained. Secondary carbohydrate alcohols are unaffected under these conditions, which allows regioselective reactions.
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