Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 14, Pages 4273-4275Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05487a
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Funding
- Hong Kong University Grants Committee [AoE/P-03-08]
- GRF [CityU 101607]
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The manganese(V) nitrido complex (PPh4)(2)[Mn(N)(CN)(4)] is an active catalyst for alkene epoxidation and alcohol oxidation using H2O2 as an oxidant. The catalytic oxidation is greatly enhanced by the addition of just one equivalent of acetic acid. The oxidation of ethene by this system has been studied computationally by the DFT method.
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