Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 1, Pages 556-558Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02220a
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Funding
- Office of Science, Office of Basic Energy Sciences of the US Department of Energy [DE-AC02-05CH11231]
- IBM
- Stanford Non-Volatile Memory Technology Research Initiative (NMTRI)
- Ernest Orlando Lawrence Postdoctoral Fellowship
- Office of Science, Department of Energy
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A general, efficient method is demonstrated for exchanging native oxyanionic ligands on inorganic nanocrystals with functional trimethylsilylated (TMS) chalcogenido ligands. In addition, newly synthesized TMS mixed chalcogenides leverage preferential reactivity of TMS-S bonds over TMS-O bonds, enabling efficient transfer of luminescent nanocrystals into aqueous media with retention of their optical properties.
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