Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 11, Pages 3177-3179Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05408a
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Funding
- US Department of Energy through the Office of Science Basic Energy Sciences Research [DE-FC36-05GO15051]
- Energy Efficiency and Renewable Energy Chemical Hydrogen Storage Center of Excellence
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Significant advantages result from combining the disparate hydrogen release pathways for ammonia-borane (AB) dehydrogenation using ionic liquids (ILs) and transition metal catalysts. With the RuCl2(PMe3)(4) catalyst precursor, AB dehydrogenation selectivity and extent are maximized in an IL with a moderately coordinating ethylsulfate anion.
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