Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 22, Pages 6353-6355Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11299f
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- Deutsche Forschungsgemeinschaft
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The reaction of the basic bismuth nitrate [Bi6O4(OH)(4)](NO3)(6)center dot H2O with sodium methacrylate in DMSO gave [Bi38O45(OMc)(24)(DMSO)(9)]center dot 2DMSO center dot 7H(2)O (OMc = O2CC3H5), which is highly soluble in organic solvents. By copolymerization of the bismuth oxido cluster with methyl methacrylate transparent, radiopaque organic-inorganic hybrid materials were obtained.
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