4.7 Article

Highly porous and robust scandium-based metal-organic frameworks for hydrogen storage

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 29, Pages 8304-8306

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11168j

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Funding

  1. EPSRC
  2. University of Nottingham
  3. Royal Society
  4. ERC
  5. CONACyT Mexico
  6. Royal Society Leverhulme Trust
  7. EPSRC [EP/I020942/1, EP/I011870/1] Funding Source: UKRI
  8. Engineering and Physical Sciences Research Council [EP/C528964/1, EP/I020942/1, EP/I011870/1] Funding Source: researchfish

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The metal-organic frameworks NOTT-400 and NOTT-401, based on a binuclear [Sc-2(mu(2)-OH)(O2CR)(4)] building block, have been synthesised and characterised; the desolvated framework NOTT-401a shows a BET surface area of 1514 m(2) g(-1) with a total H-2 uptake of 4.44 wt% at 77 K and 20 bar.

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