Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 44, Pages 12134-12136Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15241f
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Funding
- Science Foundation Ireland [08/RFP/PHY1366, 09/IN.1/B2650]
- Irish Research Council for Science, Engineering and Technology
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A strong molecule-surface interaction between free-base-tetra(4-bromophenyl)-porphyrin and Cu(111) results in a distortion of both the molecule and the underlying copper surface in the vicinity of the molecule. This in turn leads to the formation of an intermediate complex due to bonding between the iminic nitrogens and surface copper atoms.
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