4.7 Article

Pd(0)/Au(I) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(I)-complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 18, Pages 5172-5174

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11055a

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Funding

  1. Fulbright Foreign Student Program
  2. National Institute of General Medicine [GM-60578]
  3. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM060578] Funding Source: NIH RePORTER

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A Pd(II)-catalyzed homo-coupling of Au(I)-aryls is reported. The reaction is driven by a Pd(0)/Au(I) redox reaction that generates a gold mirror and Pd(II), and illustrates one of the challenges for developing dual catalytic Au-Pd systems.

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