4.7 Article

Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 14, Pages 4255-4257

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05491g

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Funding

  1. MIUR Italy [2007C8RW53]
  2. United States National Institutes of Health [CA 132861]
  3. NATIONAL CANCER INSTITUTE [R01CA132861] Funding Source: NIH RePORTER

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Mono- and di-substituted beta-nitro derivatives have been obtained from the reaction of ttcorrFeCl with sodium nitrite in refluxing DMF. This result is unprecedented for iron corrolates and further evidences the non-innocent character of the corrole ligand.

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