Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 17, Pages 5079-5081Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10708a
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Funding
- Research Grants Council of Hong Kong [GRF: PolyU5014/10P]
- PolyU Internal Grant [A-PG13]
- UGC [SEG PolyU01]
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A new family of phosphine ligands bearing a bulky carbazolyl scaffold is described. With the combination of ligand 2a and Pd(OAc)(2), difficult tri-ortho-substituted biaryl couplings are accomplished smoothly. In particular, the catalyst loading as low as 0.02 mol% of Pd for non-activated 2,6-disubstituted aryl chloride coupling can be achieved.
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