4.7 Article

Controlled hydrogenation of P(VDF-co-CTFE) to prepare P(VDF-co-TrFE-co-CTFE) in the presence of CuX (X = Cl, Br) complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 15, Pages 4544-4546

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc00106j

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Funding

  1. National Natural Science Foundation of China [50903065]
  2. Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry

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An environmentally friendly and controllable P(VDF-co-CTFE) hydrogenation route involving the transition-metal complex mediated radical chain transfer reaction is successfully developed to synthesize P(VDF-co-CTFE-co-TrFE). The typical transition metal catalysts of ATRP reaction could be applied in this process.

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