4.7 Article

A highly efficient precatalyst for amination of aryl chlorides: synthesis, structure and application of a robust acenaphthoimidazolylidene palladium complex

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 45, Pages 12358-12360

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15503b

Keywords

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Funding

  1. National Natural Science Foundation of China [20902001]
  2. Shanghai Municipal and Technology Commission [2010MCIMKF04, 10A1400500]
  3. Shanghai Leading Academic Discipline Project [B108]

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A robust palladium NHC complex was synthesized and exhibits exceptional activity and selectivity as a precatalyst in the amination of aryl chlorides and tolerates a wide range of substrates at low catalyst loadings.

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