4.7 Article

Synthesis of two-dimensional phenylene-boroxine networks through in vacuo condensation and on-surface radical addition

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 45, Pages 12355-12357

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13896k

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Funding

  1. Nanosystems-Initiative Munich (NIM) cluster of excellence
  2. Elitenetzwerk Bayern
  3. Verband der Chemischen Industrie

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We report on covalent two-dimensional phenylene-boroxine hybrid-networks that were synthesized under ultra-high vacuum conditions from doubly functionalized monomers through thermally activated condensation prior to deposition and successive heterogeneously catalyzed radical addition on Ag(111). Structural properties were characterized in situ by high resolution Scanning-Tunneling-Microscopy (STM).

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