4.7 Article

Sulfate encapsulation in a metal-assisted capsule based on a mono-pyridylurea ligand

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 10, Pages 2880-2882

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03043k

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Funding

  1. National Natural Science Foundation of China [20872149]

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A sulfate-encapsulating complex, [(CuL6)-L-1]center dot 3[(CuL2)-L-2(DMF)(4)](SO4)(4) (1, L = N-(1-naphthyl)-N'-(3-pyridyl)urea) is synthesized in which two C-3-clefts of the octahedral complexes interdigitate to form a cavity to encapsulate the sulfate ion by six urea groups.

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