4.7 Article

Homochiral 3D metal-organic frameworks from chiral 1D rods: 6-way helical packing

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 33, Pages 9402-9404

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12908b

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Funding

  1. National Research Foundation of Korea (NRF) [2009-0053318, 2011-0016303]
  2. DOE by Battelle [DE-AC05-76RL01830]

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The chiral 3D MOFs resulted from the packing of chiral 1D SBBs were studied. It was demonstrated that the final packing pattern is sensitively dependent on the dimension of SBBs. In addition, we were able to identify a new plywood-like network from ligand 2H(2) exhibiting an unprecedented six-way chiral helical packing motif, which extends the list of invariant rod packings.

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