Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 33, Pages 9417-9419Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13515e
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Selective modification of the C-terminal amide in peptides to dihydrooxazine (a novel stable imidate isostere) by intramolecular nucleophilic cyclo-O-alkylation of the corresponding N-(3-bromopropyl)amides results in constraining of the C-terminal residue in natively disallowed conformations both in crystals and in solution.
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