4.7 Article

Effects of flow-selectivity on self-assembly and auto-organization processes: an example

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 30, Pages 8551-8553

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13138a

Keywords

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Funding

  1. Spanish Government [AYA2009-13920-C02-01-02]
  2. COST [CM0703]
  3. MICINN of the Spanish Government [SB2009-0206]

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The homoassociation of H(4)TPPF(5)S(3) leads to different J-aggregates depending on whether solutions are shaken (homogenization) or stirred magnetically (square-section flask). Vortex stirring due to the generation of laminar flows decreases lateral diffusion therefore it inhibits cluster-to-cluster aggregation mechanisms.

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