4.7 Article

Chemical and photochemical oxidation of organic substrates by ruthenium aqua complexes with water as an oxygen source

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 31, Pages 8949-8951

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12558c

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Funding

  1. National Basic Research Program of China (973 program) [2009CB220009]
  2. National Natural Science Foundation of China [20923006]
  3. Fundamental Research Funds for the Central Universities [DUT11LK29]
  4. State Key Laboratory of Fine Chemicals
  5. Swedish Energy Agency
  6. K&A Wallenberg Foundation

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Two ruthenium aqua complexes were shown to be effective catalysts in chemical and photochemical oxidation of hydrocarbons. A remarkable activity (up to 90% yield and 100% selectivity) was performed in conversion of sulfide to sulfoxide by homogeneous photooxidation.

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