Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 39, Pages 11146-11148Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14262c
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Funding
- National Natural Science Foundation of China [20871088, 90922018]
- State Key Laboratory of Organometallic Chemistry
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- SooChow Scholar Program
- Suzhou University
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Reactions of [H4L][PF6](4) with 4 equiv. of Mn(OAc)(2)center dot 4H(2)O in the presence of air gave rise to a mononuclear Mn(III)-superoxo complex [Mn(III)L(O-2)(H2O)](PF6)(2), which contains a bowl-shaped cationic structure with a D-4d symmetry. It has an unprecedented linear end-on Mn(III)-O-2 unit and exhibited good efficiency and selectivity in the catalytic oxidation of alkenes with O-2 plus isobutyraldehyde under mild conditions.
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