4.7 Article

Fused perylenebisimide-carbazole: new ladder chromophores with enhanced third-order nonlinear optical activities

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 38, Pages 10749-10751

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14071j

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Funding

  1. National Natural Science Foundation of China [20876022, 60978055]
  2. Fundamental Research Funds for the Central Universities [DUT10ZD114]

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A series of ladder chromophores featuring planar structures of fused perylenebisimide and carbazole have been efficiently synthesized via photocyclization under sun light. Compared to N,N'-bis(3-pentyl) perylenebisimide (PBI-1), they show remarkably enhanced nonlinear properties.

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