4.7 Article

Synthesis and chiroptical properties of ferrocene-[4]-helicenequinones: kinetic resolution of a planar-chiral diene

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 28, Pages 8103-8105

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12921j

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Funding

  1. MICINN [CTQ2008-04691]
  2. Comunidad de Madrid and European Social Fund [SOLGEMAC-S2009/ENE-1617]

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Both enantiomers of ferrocene [4]-helicenequinone 6, showing planar and helical chiralities, have been synthesized with very high optical purities using, as the key step, a kinetic resolution process between planar-chiral racemic ferrocene diene 2 and enantiopure sulfinyl benzoquinone (S)-3.

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