Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 28, Pages 7980-7982Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11725d
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [20108010, 23750014]
- KOSEF/MEST through WCU, Korea [R31-2008-000-10010-0]
- NSF
- NSF-EPSCoR
- Australian Research Council, Australia [DP0208776]
- Grants-in-Aid for Scientific Research [20108001, 20108010] Funding Source: KAKEN
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Multiple photosynthetic reaction centres have successfully been constructed using supramolecular complexes of zinc porphyrin dendrimers [D(ZnP)(n): n = 4, 8, 16] with fulleropyrrolidine bearing a pyridine ligand (C(60)py). Efficient energy migration occurs completely between the ZnP units of dendrimers prior to the electron transfer with increasing the generation of dendrimers to attain an extremely long charge-separation lifetime.
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