4.7 Article

Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)3]2+ driven by supramolecular heteromeric fluorous carboxylate-carboxylic acid H-bond interactions

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 29, Pages 8250-8252

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12641e

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Funding

  1. University of Bordeaux 1
  2. CNRS
  3. European Research Council under the European Community [208702]
  4. Region Aquitaine

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The Ru(bipy)(3) dication is efficiently and reversibly transferred into perfluorocarbons due to the formation of a highly fluorophillic hydrogen-bonded fluorous carboxylate-carboxylic acid counter-anion, whilst retaining key luminescence and photosensitizer characteristics, for example in singlet oxygen production.

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