4.7 Article

Photoconduction in [Fe(Htrz)(2)(trz)](BF4)center dot H2O nanocrystals

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 34, Pages 9663-9665

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11441g

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Funding

  1. ANR Agency
  2. GIS-Advanced Materials in Aquitaine (AMA)

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Sub-micron-sized [Fe(Htrz)(2)(trz)](BF4)center dot H2O nanoparticles that exhibit a spin crossover transition are positioned between Au electrodes with sub-100 nm separation. After voltage poling, samples exhibit unexpected large conductivity, with photoconductance and photovoltaic behavior.

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