Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 24, Pages 6915-6917Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11358e
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Funding
- National Natural Science Foundation of China [20733004, 20821120291, 91023013, 20821003]
- National Key Project on Basic Research [2011CB808700, 2011CB932300]
- Chinese Academy of Sciences
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The co-adsorption of trinitrotoluene (TNT), a typical pi-electron acceptor, and triphenylene (TP), a typical pi-electron donor, on a Au(111) surface was investigated by in situ Electrochemical Scanning Tunneling Microscopy (ECSTM). DFT calculations proved that parallelly stacked and well-overlapped TP and TNT molecules can form Donor-Acceptor dyads through intermolecular pi-pi charge transfer, which agree well with the experimental results in the present work.
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