Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 24, Pages 6852-6854Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11859e
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Funding
- Fonds der Chemischen Industrie (FCI)
- DFG [SFB 583]
- DBU
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The intermolecular interactions between a ruthenium-based photosensitizer ([Ru(tbbpy)(2)(biH(2))](2+)) and a molecular metal oxide ([beta-Mo8O26](4-)) are investigated in solution and in the solid state. The supramolecular interactions were studied using H-1-NMR, UV-Vis and emission spectroscopy, ESI mass spectrometry and single-crystal X-ray diffraction. The formation of supramolecular aggregates was observed both in the crystal lattice and in solution. In addition, it is shown that aggregation in solution can be controlled by the competitive formation of ion pairs.
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