4.7 Article

Group 4 metal initiators for the controlled stereoselective polymerization of lactide monomers

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 16, Pages 4796-4798

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10149h

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Funding

  1. Fonds der Chemischen Industrie

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Group 4 metal initiators with a tetradentate bis(phenolato) ligand polymerized meso-lactide efficiently under ring-opening to give syndiotactic polylactide. L-Lactide was converted faster than rac-lactide and meso-lactide.

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