Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 9, Pages 2679-2681Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05160h
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A new protocol for the Cu-catalysed asymmetric conjugate addition of Grignard reagents to coumarins has been developed. The corresponding products are formed in high yields and enantioselectivities. Through a sequential protocol involving conjugate addition followed by nucleophilic ring opening of the chiral enolate, chiral esters and amides are readily accessible.
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