4.7 Article

Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 7, Pages 2137-2139

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04636a

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Funding

  1. Deutsche Forschungsgemeinschaft [Ba 1372-10]
  2. Fonds der Chemischen Industrie

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A chiral Mn(salen)complex exhibiting two lactam binding sites at two rigid 1,5,7-trimethyl-3-azabicyclo[3.3.1]nonan-2-one skeletons is capable of enantioselective sulfoxidation due to spatially remote substrate hydrogen bonding.

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