4.7 Article

Thermodynamically controlled self-sorting of hetero-bimetallic metallo-supramolecular macrocycles: what a difference a methylene group makes!

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 6, Pages 1830-1832

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04476h

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Funding

  1. Deutsche Forschungsgemeinschaft
  2. Center of Supramolecular Interactions
  3. Studienstiftung des Deutschen Volkes

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P-31 NMR and tandem MS experiments provide clear evidence for the thermodynamically controlled self-assembly of hetero-bimetallic metallo-supramolecular macrocycles through self-sorting caused by different ancillary ligands.

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