4.7 Article

Hyper-thin organic membranes with exceptional H-2/CO2 permeation selectivity: importance of ionic crosslinking and self-healing

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 8, Pages 2387-2389

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04600k

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Funding

  1. Department of Energy, Office of Basic Energy Sciences [DE-FG02-05ER15720]

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Single Langmuir-Blodgett (LB) bilayers derived from calix[n]arene-based surfactants (n = 4, 5 and 6) and poly(acrylic acid) (PAA) exhibit exceptional H-2/CO2 permeation selectivities. Evidence for the importance of ionic crosslinking and self-healing processes is presented.

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