Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 23, Pages 6626-6628Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05805j
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- French ANR
- University Louis Pasteur
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Combining diaryl-calixarenyl phosphines with [Ni(cod)(2)] resulted in highly active Kumada-Tamao-Corriu cross-coupling catalysts. With one of the ligands, TOFs up to 439 000 mol(ArBr) mol(Ni)(-1) h(-1) were observed in the reaction of 1-bromonaphthalene with PhMgBr. The systems were also found to be active at room temperature with aryl chlorides.
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